![]() +T) is identified by assigning the TRIR spectra with help ofĭFT calculations. ![]() Of the adenine radical cation species ( A System to generate purine radical cations. GC base pairs and partially so in the presence of an AT base-pair The dppz-localized states are fully quenched when bound by Spectra (TA) of 1 following excitation in the regionīetween 350 to 400 nm reveal the presence of relatively long-livedĭppz-centered states which eventually yield the emissive metal-centered The time-resolved infrared (TRIR) and visible absorption State UV/visible absorption and luminescence spectroscopic methods,Īnd the emission of 1 is found to be quenched in all ![]() With varying AT content (0–100%) have been studied by steady The interactions ofĮnantiomers of 1 with natural DNA or with oligodeoxynucleotides The participation of the excited states of 3+ ( 1) (TMP = 3,4,7,8-tetramethyl-1,10-phenanthroline ĭppz = dipyridophenazine) in DNA photoreactions. ![]() Of their long-lived metal-centered excited states. DNA photo-oxidation and synthetic photocatalyticĪctivity of chromium polypyridyl complexes is dominated by consideration ![]()
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